Carbonation in Lambic: Difference between revisions
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Carbonation forms one of the most important parts of the lambic-drinking experience. Unlike most other styles for which carbonation only exists in a narrow | Carbonation forms one of the most important parts of the lambic-drinking experience. Unlike most other styles for which carbonation only exists in a narrow bandb of concentrations, lambics span the range from entirely still to some of the most carbonated beers brewed anywhere in the world[CraftBeerPDF, PrinciplesOfBrewingScience,GuinardLambic]. Further, unusual carbonation states, such as the "Loerik" or "Lazy" and "Doesjel" or "snoozer" guezes (examples from [[Cantillon_Loerik|Cantillon]], [[Lindemans_Loerik|Lindemans]], and two from 3 Fonteinen, [[3_Fonteinen_Doesjel|1]] [[3_Fonteinen_Golden_Doesjel|2]]) that fail to carbonate as normal, are often highly sought-after experiences, and some otherwise-still lambics may carbonate over long years of ageing. Carbonation may also decrease as CO<sub>2</sub> can escape from a bottle, particularly over long timescales where the cork may become compromised. | ||
==Overview== | ==Overview== | ||
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Measurements of carbonation can be reported in volumes of CO<sub>2</sub> dissolved in the beer. By dividing both by the volume of the liquid, we arrive at a dimensionless number called "volumes of CO<sub>2</sub>". So if one liter of carbon dioxide at cellar temperature and pressure ("CTP", 55 F, 1 atm) is dissolved in one liter of lambic, we may say that this beer contains "one volume of CO<sub>2</sub>". As the molar volume of CO<sub>2</sub> at CTP is 0.043 mol/l [NIST WEBBOOK], we can convert from "volumes of CO<sub>2</sub>" to molarity by multiplying the former by 0.043. Note that this measures the volume of CO<sub>2</sub> applied, and thus the total carbon in the system irrespective of whether it's in the form of aqueous CO<sub>2</sub>, carbonic acid, or any of its deprotonations. | Measurements of carbonation can be reported in volumes of CO<sub>2</sub> dissolved in the beer. By dividing both by the volume of the liquid, we arrive at a dimensionless number called "volumes of CO<sub>2</sub>". So if one liter of carbon dioxide at cellar temperature and pressure ("CTP", 55 F, 1 atm) is dissolved in one liter of lambic, we may say that this beer contains "one volume of CO<sub>2</sub>". As the molar volume of CO<sub>2</sub> at CTP is 0.043 mol/l [NIST WEBBOOK], we can convert from "volumes of CO<sub>2</sub>" to molarity by multiplying the former by 0.043. Note that this measures the volume of CO<sub>2</sub> applied, and thus the total carbon in the system irrespective of whether it's in the form of aqueous CO<sub>2</sub>, carbonic acid, or any of its deprotonations. | ||
Lambic ranges from still lambic with 0 volumes of CO<sub>2</sub> (0 molar) to upwards of 5 volumes of CO<sub>2</sub> (0.2 molar) in the case of some highly-carbonated guezes [REF]. | |||
Measurements of carbonation in lambic are shown below along with selected other styles and carbonated beverages for comparison: | Measurements of carbonation in lambic are shown below along with selected other styles and carbonated beverages for comparison: | ||